解:因为 \(f( - x) = - \frac{1}{3}{x^3} - 4x = - f(x),\therefore f(x)\) 是奇函数,
因为 \(f\left( {{a_1} + 2} \right) = 100\),\(f\left( {{a_{2022}} + 2} \right) = - 100\),所以 \(f\left( {{a_1} + 2} \right) = - f({a_{2022}} + 2)\),
所以 \({a_1} + 2 + {a_{2022}} + 2 = 0\),所以 \({a_1} + {a_{2022}} = - 4\),
所以 \({S_{2022}} = \frac{{2022}}{2}({a_1} + {a_{2022}}) = - 4044\). 故选:A